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An amount of heat dQ absorveb by a body causes a rise dT in its temperature given by dQ = CdT, where C is heat capacity.
An equation of state f(p,v,t)=0 describes a surface in (pvt) space. A reversible transformation can be represented by a continuous path _ the surface; an irreversible transformation can be represented cannot. On
Definition: adiabatic process a process which proceeds without transfer of heat
Definition: Carnot Cycle PV cycle bounded by two isotherms and two adiabatic lines
Definition: Extensive quantities Quantities proportional to the amount of matter present
Definition: intensive quantities Quantities independent of the amount of matter present
Entropy, in terms of dS dS = dQ/T
Equation: Helmholz free energy A = U – TS
First law of thermodynamics dU = dQ – dW
U internal energy
Q heat
W == work done
Ideal gas law equation PV=NkT
k : Boltzmann’s constant
T: Ideal gas temp, in K
In a PV diagram, the work done in one cycle of a closed path is… ...the area enclosed by the path.
N (number of particles) = n(R/k), where n is _ and R/k is _ Number of moles, and Avogadro’s Number
Second law of thermodynamics "heat does not flow uphill"
(there does not exist a thermodynamic transformation whose SOLE effect is to deliver heat from a reservoir of lower temperature to a reservoir of higher temperature)
Third law of Thermodynamics The entropy of a system at absolute zero is a universal constant, which may be taken to be zero.